Chemistry Faculty Scholarship
Document Type
Article
Publication Date
9-24-2010
Publication Title
Acta Crystallographica: Section C
Keywords
Phase transformations (Physics), Polymorphism (Crystallography), Reversible processes (Thermodynamics), Hydrocarbons, Cations
Abstract
The article discusses the low-temperature phase of bis(tetrabutylammonium) octa-µ3-chlorido-hexachlorido-octahedro-hexa-tungstate, which undergoes a reversible phase transition at 268 K. The unit cells of the room- and low-temperature polymorphs of this compound are found to be closely related. The hydrocarbon chain of one of the tetrabutylammonium cations is found to be disordered at both 150 and 200 K.
First Page
m303
Last Page
m306
Volume
66
Issue
10
Repository Citation
Johnston, Dean H.; Brown, Chris M.; Yu, Andrew S.; and Gallucci, Judith C., "A low-temperature phase of bis(tetrabutylammonium) octa-l3-chloridohexachlorido- octahedro-hexatungstate" (2010). Chemistry Faculty Scholarship. 1.
https://digitalcommons.otterbein.edu/chem_fac/1
Original Citation
Johnston, Dean H., et al. "A Low-Temperature Phase Of Bis(Tetrabutylammonium) Octa-µ3-Chlorido-Hexachlorido-Octahedro-Hexa-Tungstate." Acta Crystallographica: Section C (International Union Of Crystallography - Iucr) 66.10 (2010): m303-m306. Academic Search Premier. Web. 25 Nov. 2014.
Version
Publisher's Version
Peer Reviewed
1