Chemistry Faculty Scholarship

Document Type

Article

Publication Date

9-24-2010

Publication Title

Acta Crystallographica: Section C

Keywords

Phase transformations (Physics), Polymorphism (Crystallography), Reversible processes (Thermodynamics), Hydrocarbons, Cations

Abstract

The article discusses the low-temperature phase of bis(tetrabutylammonium) octa-µ3-chlorido-hexachlorido-octahedro-hexa-tungstate, which undergoes a reversible phase transition at 268 K. The unit cells of the room- and low-temperature polymorphs of this compound are found to be closely related. The hydrocarbon chain of one of the tetrabutylammonium cations is found to be disordered at both 150 and 200 K.

First Page

m303

Last Page

m306

Volume

66

Issue

10

Original Citation

Johnston, Dean H., et al. "A Low-Temperature Phase Of Bis(Tetrabutylammonium) Octa-µ3-Chlorido-Hexachlorido-Octahedro-Hexa-Tungstate." Acta Crystallographica: Section C (International Union Of Crystallography - Iucr) 66.10 (2010): m303-m306. Academic Search Premier. Web. 25 Nov. 2014.

Version

Publisher's Version

Peer Reviewed

1

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